African Journal of
Environmental Science and Technology

  • Abbreviation: Afr. J. Environ. Sci. Technol.
  • Language: English
  • ISSN: 1996-0786
  • DOI: 10.5897/AJEST
  • Start Year: 2007
  • Published Articles: 1145

Full Length Research Paper

A study of chemical speciation of metals in aquatic bottom sediment of Aiba reservoir, Iwo, Nigeria

Godwin Oladele Olutona*, Olapeju Gifty Aribisala and Emmanuel Adewuni Akintunde
Department of Chemistry and Industrial Chemistry, Bowen University, P.M.B. 284, Iwo, Nigeria.
Email: [email protected]

  •  Accepted: 14 June 2012
  •  Published: 31 August 2012

Abstract

 

The species and total mean metal concentrations of some potentially environmental toxic metals (manganese (Mn), iron (Fe), copper (Cu), zinc (Zn), and lead (Pb)) in the sediments of Aiba reservoir were examined. The total mean value were in the order of Fe > Mn > Zn > Cu > Pb. The metal concentrations (mean ± standard deviation (SD) in µg/g dry weight) were Mn, 28 ± 0.88; Fe, 42.03 ± 1.11; Cu, 5.82 ± 0.21; Zn, 11.91 ± 0.37; and Pb, 0.44 ± 0.02. Some physico-chemical parameters of the bottom sediments were also measured and their average levels  and range are pH, 6.2 to 6.6; conductivity, 104 ± 5 µScm-1 (50 to 170 µScm-1); water absorbency, 54.66 ± 2.17 (50 to 63.3). The speciation result revealed that high levels of these metals studied (Mn, Fe, Cu, Zn, and Pb) were associated with exchangeable and carbonate bound fractions, pointing out that they are in potentially available forms and may pose serious problems to the reservoir ecosystem.

 

Key words: Bottom sediments, speciation, Aiba reservoir, metals