Journal of
Petroleum Technology and Alternative Fuels

  • Abbreviation: J. Pet. Technol. Altern. Fuels
  • Language: English
  • ISSN: 2360-8560
  • DOI: 10.5897/JPTAF
  • Start Year: 2010
  • Published Articles: 69

Full Length Research Paper

Melothria maderaspatna seed oil: A low cost feedstock for biodiesel production using crystalline manganese carbonate, a green catalyst

Y. Rajeshwer Rao
  • Y. Rajeshwer Rao
  • Department of Chemistry, Rajiv Gandhi University of Knowledge Technologies (AP-IIIT Basar campus), Mudhole, Adilabad, Andhra Pradesh-504 107, India.
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P. K. Zubaidha
  • P. K. Zubaidha
  • School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Vishnupuri, Nanded, India.
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J. Narender Reddy
  • J. Narender Reddy
  • Department of Chemistry, Government City College, High Court Road, Hyderabad-500 002, India
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D. D. Kondhare
  • D. D. Kondhare
  • School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Vishnupuri, Nanded, India.
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S. Sushma Deshmukh
  • S. Sushma Deshmukh
  • School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Vishnupuri, Nanded, India.
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P. S. Santhoshi
  • P. S. Santhoshi
  • Department of Chemistry, Government City College, High Court Road, Hyderabad-500 002, India
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Varala Ravi
  • Varala Ravi
  • Department of Chemistry, Rajiv Gandhi University of Knowledge Technologies (AP-IIIT Basar campus), Mudhole, Adilabad, Andhra Pradesh-504 107, India.
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  •  Accepted: 04 March 2013
  •  Published: 31 May 2013

Abstract

 

This research focuses on the production of biodiesel from low cost feedstock such asMelothria madraspatana seed oil via MnCO3 catalyzed transesterification process at 60°C, investigating the effects of process parameters such as molar ratio of feedstock to methanol, catalyst quantity, and reaction time on biodiesel yield. The biodiesel was successfully produced via transesterification process from low cost feedstock. The optimum parameters for maximum biodiesel yields were found to be methanol/oil molar ratio of 5:1, catalyst concentration of 1 wt% of oil, and reaction period of 75 min. The maximum biodiesel yield at the optimum condition was 93%. The fuel properties of biodiesel from M. madraspatana seed oil were also investigated and compared with those of American Society for Testing and Materials (ASTM) biodiesel standards. Crystalline manganese carbonate was found to be environmentally friendly, easy to handle and non-corrosive green catalyst for the production of biodiesel from M. madraspatana. The results demonstrated high potential of producing economically viable biodiesel from low cost feed stocks with proper optimization of the process parameters.

 

 

Key words: Biodiesel, Melothria madraspatana seed oil, MnCO3, fatty acid methyl esters, green catalyst