International Journal of
Physical Sciences

  • Abbreviation: Int. J. Phys. Sci.
  • Language: English
  • ISSN: 1992-1950
  • DOI: 10.5897/IJPS
  • Start Year: 2006
  • Published Articles: 2569

Full Length Research Paper

Inhibition effect of potassium dichromate on the corrosion protection of mild steel reinforcement in concrete

C. A. Loto1,2*, O. A. Omotosho2 and A. P. I. Popoola1
1Department of Chemical and Metallurgical Engineering, Tshwane University of Technology, Pretoria, South Africa. 2Department of Mechanical Engineering, Covenant University, P.M.B. 1023, Ota, Nigeria.
Email: [email protected]

  •  Accepted: 11 April 2011
  •  Published: 04 May 2011

Abstract

The inhibition of potassium dichromate on the corrosion protection of mild steel embedded in concrete and partially immersed in sulphuric acid and sodium chloride environments was evaluated at ambient temperatures. The experiments were performed using electrochemical potential monitoring method. Varying quantities of the inhibitor was used. In the NaCl test medium, the effectiveness of the inhibitor improved as higher concentration was used. The best inhibition was achieved in the reinforced concrete sample admixed with 9 g potassium dichromate. Steel-reinforced concrete sample admixed with 3 and 9 g potassium dichromate inhibitor had the highest improvement in compressive strength. The potassium dichromate inhibitor was most effective amongst other inhibitor concentrations used when 7.5 g was admixed with the sample in the H2SO4medium. The sulphuric acid medium had a deleterious effect on the strength of concrete test specimens.

 

Key words: Corrosion, passive/active corrosion, inhibitors, sulphuric acid, sodium chloride media.