Full Length Research Paper
Abstract
Rubber seeds from a Nigerian hybrid rubber tree were dried in an oven at 110°C for 2 h to 7 wt% moisture content and cold-screw pressed at 30°C to obtain an oil yield of 28 wt%. Chemical compositional, nuclear magnetic resonance (NMR) and Fourier transform infra-red spectroscopy (FTIR) analyses were conducted on the oil sample extracts. Chemical analysis of the oil indicated iodine value of 136.07 g I2/100 g oil, peroxide value of 9.45 O2/kg oil, saponification value of 189.5 mg KOH/g oil, and confirms its suitability for applications, such as biodiesel production, oleochemicals synthesis, polyurethane composites and water-reducible alkyd resins, pharmaceutical products, plasticizers, adhesives, and surfactants. Rubber seed oil is a promising substitute to linseed oil as semi-drying oil for oily paint formulation. 1H NMR analysis revealed that the fatty acid compositions consist of linoleic acid (34.22 wt%), oleic acid (28.6 wt%), linolenic acid (18.6 wt%), and saturated fatty acids (18.57 wt%). FTIR analysis indicated fingerprint regions of 1461 to 585 cm-1 which can be used to check adulteration of the oil. The NMR spectra (1H and 13C) of the oil are similar to those of other vegetable oils with well-identified peaks and regions that can be used to authenticate the quality of the oil.
Key words: Rubber seed oil, characterization, nuclear magnetic resonance (NMR), Fourier transform infra-red spectroscopy (FTIR), quality assessment, technical applications.
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